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By Janne-Mieke Meijer

This thesis offers an in-depth research at the impression of colloidal particle form and formation mechanism on self-organization and the ultimate crystal symmetries that may be accomplished. It demonstrates how cutting-edge X-ray diffraction thoughts can be utilized to provide precise characterizations of colloidal crystal buildings ready utilizing diversified self-assembly recommendations, and the way shrewdpermanent structures can be utilized to enquire illness formation and diffusion in-situ. some of the most striking phenomena exhibited via targeted suspensions of colloidal debris is the spontaneous self-organization into buildings with long-range spatial and/or orientational orders. The examine additionally finds the sophisticated structural diversifications that come up by way of altering the particle form from round to that of a rounded dice. specifically, the roundness of the dice corners, whilst mixed with the self-organization pathway, convective meeting or sedimentation, was once proven to persuade the ultimate crystal symmetries.

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