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By William M. Ayers

content material: resources and economics of carbon dioxide / Sol J. Barer and Kenneth M. Stern --
Carbon dioxide equilibria / James N. Butler --
Coordination of carbon dioxide to nickel : an alternate theoretical version / R.P. Messmer and H.-J. Freund --
Metal-induced variations of carbon dioxide / Donald J. Darensbourg, Christopher G. Bauch, and Cesar Ovalles --
Use of stoichiometric reactions within the layout of redox catalyst for carbon dioxide aid / Daniel L. DuBois and Alex Miedaner --
Electrocatalytic carbon dioxide relief / B. Patrick Sullivan, Mitchell R.M. Bruce, Terrence R. O'Toole, C. Mark Bolinger, Elise Megehee, Holden Thorp, and Thomas J. Meyer --
Enzymatic activation of carbon dioxide / Leland C. Allen --
Adsorptive and catalytic homes of carbon monoxide and carbon dioxide over supported steel oxides / D.G. Rethwisch and J.A. Dumesic --
Adsorption and response of carbon dioxide on zirconium dioxide / Ronald G. Silver, Nancy B. Jackson, and John G. Ekerdt --
influence of potassium at the hydrogenation of carbon monoxide and carbon dioxide over supported Rh catalysts / S.D. Worley and C.H. Dai --
Carbon dioxide aid with an electrical box assisted hydrogen insertion response / W.M. Ayers and M. Farley --
Electrochemical relief of aqueous carbon dioxide at electroplated Ru electrodes : investigations towards the mechanism of methane formation / Karl W. Frese, Jr. and David P. Summers --
Electrochemical experiences of carbon dioxide and sodium formate in aqueous recommendations / M.H. Miles and A.N. Fletcher --
Electrochemical activation of carbon dioxide / okay. Chandrasekaran and J. O'M. Bockris.

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S e v e r a l f a c t o r s e f f e c t the r a t e o f C 0 i n s e r t i o n i n t o m e t a l carbon bonds. The most n o t a b l e o f these i s the e l e c t r o n d e n s i t y a t the metal center. As i s the case f o r the h y d r i d e (vide supra), the i s o e l e c t r o n i c n e u t r a l manganese and rhenium analogues o f the group 6 a l k y l s do not undergo C 0 i n s e r t i o n . D e m o n s t r a t i o n o f the d r a m a t i c e f f e c t t h a t the e l e c t r o n d e n s i t y , a t the m e t a l c e n t e r , has on C 0 i n s e r t i o n can be seen when the e l e c t r o n d o n a t i n g p r o p e r t y o f the l i g a n d , L, i n cis-CH W(C0)„ΙΓ, i s v a r i e d .

News, 1985, 63, 10. 14. Czoukowski, M. ; Bayne, A. R. Hydrocarbon Process. 1980, 59, 103. 15. Leonard, J. D. S. Patent 4 299 981 (1981). 16. Ikaraski, T. Chem. Economy & Eng. Rev. 1980, 12, 31 17. Darensbourg, D. ; Rokicki, A. Organometallics 1982, 1, 1685. 18. Slater, S. ; Schumann, B. ; Darensbourg, M. Organometallics 1982, 1, 1662. 19. Darensbourg, D. J . ; Darensbourg, M. Y. J. Am. Chem. Soc. 1981, 103, 3223. 20. Kao, S. ; Darensbourg, M. ; Schenck, W. Organometallics 1984, 3, 871. 21. Darensbourg, D.

G. ; Abel, E. ; Pergamon Press: Oxford, 1982; Vol. 225. 11. ; Yamamoto, A. : Toyko, Japan, 1982, p 79. 12. Darensbourg, D. J . ; Ovalles, C. Chem. Tech. 1985, 15, 636. 13. Chem. Eng. News, 1985, 63, 10. 14. Czoukowski, M. ; Bayne, A. R. Hydrocarbon Process. 1980, 59, 103. 15. Leonard, J. D. S. Patent 4 299 981 (1981). 16. Ikaraski, T. Chem. Economy & Eng. Rev. 1980, 12, 31 17. Darensbourg, D. ; Rokicki, A. Organometallics 1982, 1, 1685. 18. Slater, S. ; Schumann, B. ; Darensbourg, M. Organometallics 1982, 1, 1662.

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